Randomness in atomic disorder and consequent squandering of spin-polarization in a ferromagnetically fragile quaternary Heusler alloy FeRuCrSi

Abstract

Ru${}_{2-x}$Fe${}_x$CrSi ( 0 $<$ x $<$1) system is theoretically predicted to be one of the very few known examples of robust half-metallic ferromagnet with 100\% spin polarization. Since Cr is considered to be the main contributor to magnetism, the Fe/Ru substitution is not expected to disturb its magnetic properties any significantly, and hence all Fe-containing members of the series are predicted to follow Slater-Pauling rule with a saturation magnetic moment of 2 ${\mu }_B$/f.u. However, contrarily to the theoretical expectations, some experiments rather show a linear variation of the saturation magnetization and Curie temperature with Fe (\textit{x}) substitution. The equiatomic member FeRuCrSi of this family is also considered as a technologically important material, where the band structure calculations suggest the material to be spin gapless semiconductor. Through our in-depth structural analysis of FeRuCrSi using X-ray diffraction, extended X-ray absorption fine structure and ${}^{57}$Fe Mössbauer spectrometry, we found a random disorder between Fe and Ru sites, while the magnetic moment in this system is actually contributed by Fe atoms, questioning the very basic foundation of the half-metallic character proposed by all theoretical calculations on Ru${}_{2-x}$Fe${}_x$CrSi series. Our Mössbauer result also envisions a rather rare scenario where the main physical properties are intricately correlated to the chemistry of the material in the form of random atomic disorder on a localised scale.

References in corpus (9)

• A New Spin Gapless Semiconductors Family: Quaternary Heusler Compounds
• Coexisting structural disorder and robust spin-polarization in half-metallic FeMnVAl
• Experimental observation of spin glass state in highly disordered quaternary Heusler alloy FeRuMnGa
• FeRhCrSi: A new spin semimetal with room temperature spin-valve behavior
• Rare observation of spin-gapless semiconducting characteristics and related band topology of quaternary Heusler alloy CoFeMnSn
• High spin-polarization in a disordered novel quaternary Heusler alloy FeMnVGa
• 4d-element induced improvement of structural disorder and development of weakly re-entrant spin-glass behaviour in NiRuMnSn
• Restructuring disorder: Transformation from the antiferromagnetic order in Fe2VSi to the ferromagnetic state in FeRuVSi by substitution of a non-magnetic element
• Randomness in atomic disorder and consequent squandering of spin-polarization in a ferromagnetically fragile quaternary Heusler alloy FeRuCrSi

Cited by in corpus (1)

• Randomness in atomic disorder and consequent squandering of spin-polarization in a ferromagnetically fragile quaternary Heusler alloy FeRuCrSi