Photodesorption efficiency of OH radical on the ice surface in the wavelength range from ultraviolet to visible

Abstract

The photodesorption efficiencies of the hydroxyl (OH) radical from the water ice surface were measured in the range of 310-700 nm for the first time. Although isolated H${}_2$O molecules and OH radicals do not absorb visible photons, the photodesorption of OH interacting with the ice surface was found to occur by a one-photon process in the entire visible range. The photodesorption efficiency strongly depended on the wavelength, and the analyses of photodesorption cross sections indicated that only strongly bound OH radicals were desorbed at longer wavelengths, whereas both weakly and strongly bound OH radicals were desorbed at shorter wavelengths.

11 pages, 6 figures

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