Experimental and Theoretical Bulk Phase Diagram and Interfacial Tension of Ouzo

Abstract

Ouzo is a well-known drink in Mediterranean countries, with ingredients water, alcohol and trans-anethole oil. The oil is insoluble in water, but completely soluble in alcohol, so when water is added to the spirit, the available alcohol is depleted and the mixture exhibits spontaneous emulsification. This process is commonly known as the louche or Ouzo effect. Although the phase boundaries of this archetypal ternary mixture are well known, the properties of coexisting phases have not previously been studied. Here, we present a detailed experimental investigation into the phase behaviour, including tie-lines connecting coexisting phases, determination of the critical point (also called the plait point in ternary systems) and measurements of the surface tension and density for varying alcohol concentrations. Additionally, we present a theory for the thermodynamics and phase diagram of the system. With suitable selection of the interaction parameters, the theory captures nearly all features of the experimental work. This simple model can be used to determine both bulk and non-uniform (e.g. interfacial) properties, paving the way for a wide range of future applications of the model to ternary mixtures in general. We show how our accurate equilibrium phase diagram can be used to provide improved understanding of non-equilibrium phenomena.

15 pages, 9 figures

References in corpus (6)

• Evaporation-triggered microdroplet nucleation and the four life phases of an evaporating Ouzo drop
• Liquid drops on a surface: using density functional theory to calculate the binding potential and drop profiles and comparing with results from mesoscopic modelling
• Critical Casimir Forces and Colloidal Phase Transitions in a Near-Critical Solvent : A Simple Model Reveals a Rich Phase Diagram
• Binding potential and wetting behaviour of binary liquid mixtures on surfaces
• Nudged Elastic Band calculation of the binding potential for liquids at interfaces
• Stability of nanoparticle laden aerosol liquid droplets

Cited by in corpus (4)

• Learning the bulk and interfacial physics of liquid-liquid phase separation with neural density functionals
• Coexisting multiphase and interfacial behaviour of ouzo
• Interactions between droplets in immiscible liquid suspensions and the influence of surfactants
• Upstream motion of oil droplets in co-axial Ouzo flow due to Marangoni forces