Spontaneous gap opening and potential excitonic states in an ideal Dirac semimetal Ta${}_2$Pd${}_3$Te${}_5$

Abstract

The opening of an energy gap in the electronic structure generally indicates the presence of interactions. In materials with low carrier density and short screening length, long-range Coulomb interaction favors the spontaneous formation of electron-hole pairs, so-called excitons, opening an excitonic gap at the Fermi level. Excitonic materials host unique phenomenons associated with pair excitations. However, there is still no generally recognized single-crystal material with excitonic order, which is, therefore, awaited in condensed matter physics. Here, we show that excitonic states may exist in the quasi-one-dimensional material Ta${}_2$Pd${}_3$Te${}_5$, which has an almost ideal Dirac-like band structure, with Dirac point located exactly at Fermi level. We find that an energy gap appears at 350 K, and it grows with decreasing temperature. The spontaneous gap opening is absent in a similar material Ta${}_2$Ni${}_3$Te${}_5$. Intriguingly, the gap is destroyed by the potassium deposition on the crystal, likely due to extra-doped carriers. Furthermore, we observe a pair of in-gap flat bands, which is an analog of the impurity states in a superconducting gap. All these observations can be properly explained by an excitonic order, providing Ta${}_2$Pd${}_3$Te${}_5$ as a new and promising candidate realizing excitonic states.

9 pages, 5 figures

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• Excitonic Instability in Ta2Pd3Te5 Monolayer
• Collective modes and Raman response in Ta${}_2$NiSe${}_5$
• First-principles design of excitonic insulators: A review
• Spin-Triplet Excitonic Insulator in the Ultra-Quantum Limit of HfTe5
• Unconventional excitonic insulators in two-dimensional topological materials
• Engineering excitonic metal-insulator transitions in ultra-thin doped copper sulfides