Ultracold coherent control of molecular collisions at a Förster resonance
arXiv:2312.13726 · doi:10.1103/PhysRevA.109.L061303
Abstract
We show that the precise preparation of a quantum superposition between three rotational states of an ultracold dipolar molecule generates controllable interferences in their two-body scattering dynamics and collisional rate coefficients, at an electric field that produces a Förster resonance. This proposal represents a feasible protocol to achieve coherent control on ultracold molecular collisions in current experiments. It sets the basis for future studies in which one can think to control the amount of each produced pairs, including trapped entangled pairs of reactants, individual pairs of products in a chemical reaction, and measuring each of their scattering phase-shifts that could envision ``complete chemical experiments" at ultracold temperatures.
11 pages, 4 figures
References in corpus (30)
- A High Phase-Space-Density Gas of Polar Molecules
- Strongly correlated 2D quantum phases with cold polar molecules: controlling the shape of the interaction potential
- Cold molecules: Progress in Quantum Engineering of Chemistry and Quantum Matter
- Dipole blockade in a cold Rydberg atomic sample
- Stable Topological Superfluid Phase of Ultracold Polar Fermionic Molecules
- Evaporation of microwave-shielded polar molecules to quantum degeneracy
- Observation of Bose-Einstein Condensation of Dipolar Molecules
- On-Demand Entanglement of Molecules in a Reconfigurable Optical Tweezer Array
- The hyperfine energy levels of alkali metal dimers: ground-state polar molecules in electric and magnetic fields
- Resonant collisional shielding of reactive molecules using electric fields
- Repulsive shield between polar molecules
- Probing site-resolved correlations in a spin system of ultracold molecules
- Dipolar evaporation of reactive molecules to below the Fermi temperature
- Tuning of dipolar interactions and evaporative cooling in a three-dimensional molecular quantum gas
- Universal rates for reactive ultracold polar molecules in reduced dimensions
- Precision test of statistical dynamics with state-to-state ultracold chemistry
- State-to-state control of ultracold molecular reactions
- Self-bound dipolar droplets and supersolids in molecular Bose-Einstein condensates
- Collisionally Stable Gas of Bosonic Dipolar Ground State Molecules
- Electric field suppression of ultracold confined chemical rates
- Formation of ultracold molecules by merging optical tweezers
- Microwave shielding of bosonic NaRb molecules
- Tuning ultracold collisions of excited rotational dipolar molecules
- Hyperfine structure of alkali-metal diatomic molecules
- Optical shielding of destructive chemical reactions between ultracold ground-state NaRb molecules
- Ultracold field-linked tetratomic molecules
- Complete quantum coherent control of ultracold molecular collisions
- Statistical product distributions for ultracold reactions in external fields
- Electro-association of ultracold dipolar molecules into tetramer field-linked states
- Two-photon optical shielding of collisions between ultracold polar molecules