${}^{13}$C NMR observation of a nonmagnetic charge-ordered state in the organic conductor $\kappa$-(ET)${}_2$Hg(SCN)${}_2$Cl

Abstract

We investigated the local magnetism of the organic conductor, $\kappa$-(ET)${}_2$Hg(SCN)${}_2$Cl, with a quasi-triangular lattice of weakly dimerized molecules through ${}^{13}$C NMR spectroscopy. The NMR spectra and nuclear relaxation show that charge disproportionation occurs, associated with the metal-insulator transition at 31 K. The relaxation rate indicates that the paramagnetic spins in the insulating phase undergo a transition into a spin-singlet ground state with the emergence of orphan spins, a possible valence-bond-glass state. The present results are in high contrast to the spin-cluster paramagnetism of the electric dipole-liquid candidate, $\kappa$--(ET)${}_2$Hg(SCN)${}_2$Br, having nearly identical material parameters. This fact indicates that these two systems are on the verge between distinct phases in both charge and spin degrees of freedom; a spin-singlet charge-ordered state versus a spin-active Mott insulating state, competing with each other on a triangular lattice of dimerized sites.

13 pages, 9 figures, 1 table

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