Trade-offs between number fluctuations and response in nonequilibrium chemical reaction networks
arXiv:2304.04961 · doi:10.1063/5.0148662
Abstract
We study the response of chemical reaction networks driven far from equilibrium to logarithmic perturbations of reaction rates. The response of the mean number of a chemical species is observed to be quantitively limited by number fluctuations as well as the maximum thermodynamic driving force. We prove these trade-offs for linear chemical reaction networks and a class of nonlinear chemical reaction networks with a single chemical species. Numerical results for several model systems support the conclusion that these trade-offs continue to hold for a broad class of chemical reaction networks, though their precise form appears to depend sensitively on the deficiency of the network.
arXiv comment22 pages, 12 figures
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