Effects of metallic electrodes on the thermoelectric properties of zigzag graphene nanoribbons with periodic vacancies

Abstract

We theoretically analyze the thermoelectric properties of graphene quantum dot arrays (GQDAs) with line- or surface-contacted metal electrodes. Such GQDAs are realized as zigzag graphene nanoribbons (ZGNRs) with periodic vacancies. Gaps and minibands are formed in these GQDAs, which can have metallic and semiconducting phases. The electronic states of the first conduction (valence) miniband with nonlinear dispersion may have long coherent lengths along the zigzag edge direction. With line-contacted metal electrodes, the GQDAs have the characteristics of serially coupled quantum dots (SCQDs) if the armchair edge atoms of the ZGNRs are coupled to the electrodes. By contrast, the GQDAs have the characteristics of parallel QDs if the zigzag edge atoms are coupled to the electrodes. The maximum thermoelectric power factors of SCQDs with line-contacted electrodes of Cu, Au, Pt, Pd, or Ti at room temperature were similar or greater than $0.186nW/K$; their figures of merit were greater than three. GQDAs with line-contacted metal electrodes have much better thermoelectric performance than surface contacted metal electrodes.

9 pages, 12 figures and improve Fig. 2

References in corpus (7)

• Electric Field Effect in Atomically Thin Carbon Films
• Enhanced Thermoelectric Performance and Anomalous Seebeck Effects in Topological Insulators
• Frequency-selective single photon detection using a double quantum dot
• Effects of metallic contacts on electron transport through graphene
• Giant thermoelectric effect in graphene-based topological insulators with nanopores
• Atomic-scale model for the contact resistance of the nickel-graphene interface
• Large enhancement in thermoelectric efficiency of quantum dot junction due to increase of level degeneracy