paper

Seebeck Coefficient of Two-dimensional Dirac Electrons in Organic Conductor under Pressure

arXiv:2211.00966 · doi:10.1103/PhysRevB.107.195416

Abstract

The Seebeck coefficient, which is proportional to a ratio of the thermoelectric conductivity to electrical conductivity has been examined for Dirac electrons in the organic conductor -(BEDT-TTF)I [BEDT-TTF denotes a molecule given by bis(ethylenedithio)tetrathiafulvalene] under a uniaxial pressure using a two-dimensional tight-binding model with both impurity and electron--phonon (e--p) scatterings. We calculate an anomalous temperature () dependence of the Seebeck coefficient with (perpendicular to the molecular stacking axis) and , which shows with a maximum at high temperatures and with a minimum at low temperatures.The microscopic mechanism of such a sign change of is clarified in terms of the spectral conductivity. The result is compared with experiments on -(BEDT-TTF)I.

6 pages,4 figures

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