Competing quantum spin liquids, gauge fluctuations, and anisotropic interactions in a breathing pyrochlore lattice

Abstract

We use the projective symmetry group analysis to classify the quantum spin liquids on the $S=1/2$ pyrochlore magnet with a breathing anisotropy. We find 40 ${\mathbb{Z}}_2$ spin liquids and 16 $U(1)$ spin liquids that respect the $F\bar{4}3m$ space group and the time reversal symmetry. As an application, we consider the antiferromagnetic Heisenberg model, which is proposed to be the dominant interaction in the candidate material Ba${}_3$Yb${}_2$Zn${}_5$O${}_{11}$. Focusing on the $U(1)$ spin liquid ansatze, we find that only two of them are physical when restricted to this model. We present an analytical solution to the parton mean field theory for each of these two $U(1)$ spin liquids. It is revealed that one of them has gapless, while the other one has gapped, spinon excitations. The two $U(1)$ spin liquids are equal in energy regardless of the degree of breathing anisotropy, and they can be differentiated by the low-temperature heat capacity contribution from the quadratically-dispersing gapless spinons. We further show that the latter is unaffected by fluctuations of the $U(1)$ gauge field within the random phase approximation. Finally, we demonstrate that a small Dzyaloshinskii-Moriya interaction lifts the degeneracy between the two $U(1)$ spin liquids, and it eventually causes the lattice to decouple into independent tetrahedra at strong coupling. While current model parameters for Ba${}_3$Yb${}_2$Zn${}_5$O${}_{11}$ place it indeed in the decoupled regime, other candidate materials may be synthesised in the near future that realize the spin liquid states discussed in our work.

10+15 pages, 4+1 figures, 1+1 tables

References in corpus (17)

• Higher-order topological insulators and semimetals on the breathing Kagome and pyrochlore lattices
• Pyrochlore Photons: The U(1) Spin Liquid in a S=1/2 Three-Dimensional Frustrated Magnet
• Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7
• Weak magnetism and non-Fermi liquids near heavy-fermion critical points
• U(1) Gauge Theory of the Hubbard Model : Spin Liquid States and Possible Application to k-(BEDT-TTF)_2 Cu_2 (CN)_3
• Unusual liquid state of hard-core bosons on the pyrochlore lattice
• $Z_2$ spin liquid and chiral antiferromagnetic phase in Hubbard model on the honeycomb lattice: duality between Schwinger-fermion and Schwinger-boson representations
• Spin liquids on a honeycomb lattice: Projective Symmetry Group study of Schwinger fermion mean-field theory
• Experimental Realization of a Quantum Breathing Pyrochlore Antiferromagnet
• Transport Properties of a spinon Fermi surface coupled to a U(1) gauge field
• Novel Phase Transitions in the Breathing Pyrochlore Lattice: 7Li-NMR on LiInCr4O8 and LiGaCr4O8
• Observing Monopoles in a Magnetic Analog of Ice
• Magnetic Phase Diagram of the Breathing Pyrochlore Antiferromagnet LiGa1-xInxCr4O8
• Interplay of non-symmorphic symmetry and spin-orbit coupling in hyperkagome spin liquids: Applications to Na${}_4$Ir${}_3$O${}_8$
• Spin ordering induced by lattice distortions in classical Heisenberg antiferromagnets on the breathing pyrochlore lattice
• Theory of antiferromagnetic Heisenberg spins on breathing pyrochlore lattice
• Susceptibility of a spinon Fermi surface coupled to a U(1) gauge field