Higher-order corrections to spin-orbit and spin-spin tensor interactions in hydrogen molecular ions: theory and application to H
arXiv:2207.01535 · doi:10.1103/PhysRevA.106.022816
Abstract
We consider higher-order corrections to hyperfine coefficients related to the spin-orbit and spin-spin tensor interactions in hydrogen molecular ions. The -order radiative correction is derived in the NRQED framework. We present complete numerical calculations, including as well the -order relativistic correction, for the case of H. The theoretical uncertainty is reduced by more than one order of magnitude with respect to the Breit-Pauli level, down to a few ppm. We also compare our results with available rf spectroscopy data.
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