Electron transfer under the Floquet modulation in donor-bridge-acceptor systems
arXiv:2203.11558 · doi:10.1021/acs.jpca.2c03308
Abstract
Electron transfer (ET) processes are of broad interest in modern chemistry. With the advancements of experimental techniques, one may modulate the ET via such as the light-matter interactions. In this work, we study the ET under a Floquet modulation occurring in the donor-bridge-acceptor systems, with the rate kernels projected out from the exact disspaton equation of motion formalism. This together with the Floquet theorem enables us to investigate the interplay between the intrinsic non-Markovianity and the driving periodicity. The observed rate kernel exhibits a Herzberg-Teller-like mechanism induced by the bridge fluctuation subject to effective modulation.
arXiv comment10 pages, 6 figures
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Cited by in corpus (4)
- Quantum mechanics of open systems: Dissipaton theories
- Dissipatons as generalized Brownian particles for open quantum systems: Dissipaton-embedded quantum master equation
- Electron transfer in confined electromagnetic fields: a unified Fermi's golden rule rate theory and extension to lossy cavities
- Herzberg-Teller coupling in coherent multidimensional spectroscopy: analytical response functions for multilevel systems