Particle-scale modeling of the drying characteristics of colloidal suspensions
arXiv:2201.12992 · doi:10.1016/j.ces.2023.118993
Abstract
During drying of colloidal suspensions, colloidal particles can form concentrated particle layers beneath the receding free surface. The drying rate can gradually decrease with the growth of the particle layers. We construct a model to investigate how such drying characteristics is affected by interactions between particles. In this model, the formation of the particle layers is described by Langevin dynamics simulations, and the drying rate is evaluated from the permeation resistance of the particle layers. We show that the decrease in the drying rate is suppressed when the particles form aggregates by attractive interactions. The present model would enable us to predict and control the drying characteristics through the character of colloidal particles.
arXiv comment10 pages, 13 figures
References in corpus (7)
- Close packing density of polydisperse hard spheres
- Why is Random Close Packing Reproducible?
- Dynamic stratification in drying films of colloidal mixtures
- Fundamental challenges in packing problems: from spherical to non-spherical particles
- Diffusiophoresis in non-adsorbing polymer solutions: the Asakura-Oosawa model and stratification in drying films
- Many-body interactions and melting of colloidal crystals
- Stratification of drying particle suspensions: Comparison of implicit and explicit solvent simulations