Propensity rules for photoelectron circular dichroism in strong field ionization of chiral molecules

Abstract

Chiral molecules ionized by circularly polarized fields produce a photoelectron current orthogonal to the polarization plane. This current has opposite directions for opposite enantiomers and provides an extremely sensitive probe of molecular handedness. Recently, such photoelectron currents have been measured in the strong-field ionization regime, where they may serve as an ultrafast probe of molecular chirality. Here we provide a mechanism for the emergence of such strong-field photoelectron currents in terms of two propensity rules that link the properties of the initial electronic chiral state to the direction of the photoelectron current.

arXiv comment14 pages, 4 figures

References in corpus (12)

• Multiphoton detachment of electrons from negative ions
• Ultrafast Preparation and Detection of Ring Currents in Single Atoms
• Nonadiabatic tunneling in circularly polarized laser fields: Derivation of formulas
• Photoelectron circular dichroism with two overlapping laser pulses of carrier frequencies $\omega$ and $2\omega$ linearly polarized in two mutually-orthogonal directions
• Generalized perspective on chiral measurements without magnetic interactions
• Non-adiabatic Coulomb effects in strong field ionisation in circularly polarised laser fields
• Time-resolving electron-core dynamics during strong field ionization in circularly polarized fields
• Opportunities for detecting ring currents using the attoclock set-up
• Propensity rules in photoelectron circular dichroism in chiral molecules I: Chiral hydrogen
• Coulomb time delays in high harmonic generation
• Propensity rules in photoelectron circular dichroism in chiral molecules II: General picture
• Photoelectron circular dichroism in the multiphoton ionization by short laser pulses: III. Photoionization of fenchone in different regimes

Cited by in corpus (5)

• Ultrafast chirality: the road to efficient chiral measurements
• Molecular chirality and its monitoring by ultrafast X-ray pulses
• The Application of Tailored Fields for Studying Chirality and Symmetry
• Strong-field chiral imaging with twisted photoelectrons
• Enantiosensitive steering of free-induction decay