Resonance-enhanced multiphoton ionization in the x-ray regime

Abstract

Here, we report on the nonlinear ionization of argon atoms in the short wavelength regime using ultraintense x rays from the European XFEL. After sequential multiphoton ionization, high charge states are obtained. For photon energies that are insufficient to directly ionize a $1s$ electron, a different mechanism is required to obtain ionization to Ar${}^{17+}$. We propose this occurs through a two-color process where the second harmonic of the FEL pulse resonantly excites the system via a $1s\to 2p$ transition followed by ionization by the fundamental FEL pulse, which is a type of x-ray resonance-enhanced multiphoton ionization (REMPI). This resonant phenomenon occurs not only for Ar${}^{16+}$, but through multiple lower charge states, where multiple ionization competes with decay lifetimes, making x-ray REMPI distinctive from conventional REMPI. With the aid of state-of-the-art theoretical calculations, we explain the effects of x-ray REMPI on the relevant ion yields and spectral profile.

8 pages, 5 figures, one supplementary material (not included)

References in corpus (3)

• Optically-Induced Highly-Efficient Detection and Separation of Chiral Molecules through Shortcuts to Adiabaticity
• Enhanced nonlinear response of Ne${}^{8+}$ to intense ultrafast x rays
• Enhanced Self-seeding with Ultra-short Electron Beams

Cited by in corpus (1)

• Enhanced One-Color-Two-Photon Resonant Ionization in Highly Charged Ions by Fine-Structure Effects