Measuring photoexcited electron and hole dynamics in ZnTe and modeling excited state core-valence effects in transient XUV reflection spectroscopy

Abstract

Transient XUV spectroscopy is growing in popularity for the measurement of solar fuel and photovoltaic materials as it can separately measure electron and hole energies for multiple elements at once. However, interpretation of transient XUV measurements is complicated by changes in core-valence exciton and angular momentum effects after photoexcitation. Here, we report the photoexcited electron and hole dynamics for ZnTe, a promising material for CO2 reduction, following 400 nm excitation. We apply a newly developed, ab-initio theoretical approach based on density functional theory and the Bethe-Salpeter equation to accurately predict the excited state change in the measured transient XUV spectra. Electrons excited to the conduction band are measured with a thermalization rate of 70 $\pm$ 40 fs. Holes are excited with an average excess energy of ~1 eV and thermalize in 1130 $\pm$ 150 fs. The theoretical approach also allows an estimated assignment of inter- and intra-valley relaxation pathways in k-space using the relative amplitudes of the core-valence excitons.

References in corpus (5)

• Electronic structure of quantum materials studied by angle-resolved photoemission spectroscopy
• Bethe-Salpeter Equation Calculations of Core Excitation Spectra
• Direct and Simultaneous Observation of Ultrafast Electron and Hole Dynamics in Germanium
• Efficient implementation of core-excitation Bethe Salpeter equation calculations
• Differentiating Photoexcited Carrier and Phonon Dynamics in the Δ, L, and Γ Valleys of Si(100) with Transient Extreme Ultraviolet Spectroscopy