Electron-Nuclear Interactions as a Test of Crystal-Field Parameters for Low Symmetry Systems: Zeeman-Hyperfine Spectroscopy of Ho${}^{3+}$ Doped Y${}_2$SiO${}_5$

Abstract

High-resolution Zeeman spectroscopy of electronic-nuclear hyperfine levels of ${}^5{\mathrm{I}}_8\to {}^5{\mathrm{I}}_7$ transitions in Ho${}^{3+}$:Y${}_2$SiO${}_5$ is reported. Crystal-field parameters determined for the two $C_1$ symmetry sites in Er${}^{3+}$:Y${}_2$SiO${}_5$ are successfully used to model the Zeeman-hyperfine data, including the prediction of avoided crossings between hyperfine levels under the influence of an external magnetic field. The two six- and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.

References in corpus (14)

• A solid state light-matter interface at the single photon level
• Isolating and enhancing the emission of single erbium ions using a silicon nanophotonic cavity
• Coherence time of over a second in a telecom-compatible quantum memory storage material
• Dynamic decoherence control of a solid-state nuclear quadrupole qubit
• Telecommunication-wavelength solid-state memory at the single photon level
• Anisotropic rare-earth spin ensemble strongly coupled to a superconducting resonator
• Parallel single-shot measurement and coherent control of solid-state spins below the diffraction limit
• Coherent frequency up-conversion of microwaves to the optical telecommunications band in an Er:YSO crystal
• Experimental demonstration of quantum state tomography and qubit-qubit interactions for rare-earth-ion based solid state qubits
• Experimental quantum state tomography of a solid state qubit
• State Preparation by Optical Pumping in Erbium Doped Solids using Stimulated Emission and Spin Mixing
• Extending Phenomenological Crystal-Field Methods to $C_1$ Point-Group Symmetry: Characterization of the Optically-Excited Hyperfine Structure of ${}^{167}$Er${}^{3+}$:Y${}_2$SiO${}_5$
• Transferability of crystal-field parameters for rare-earth ions in Y${}_2$SiO${}_5$ tested by Zeeman spectroscopy
• Electron paramagnetic resonance enhanced crystal field analysis for low point-group symmetry systems: C${}_{2v}$ sites in Sm${}^{3+}$:CaF${}_2$/SrF${}_2$

Cited by in corpus (8)

• Radiative heat transfer in low-symmetry Bravais crystal
• Prediction of the Optical Polarization and High Field Hyperfine Structure Via a Parametrized Crystal-Field Model for the Low Symmetry Centers in Er${}^{3+}$ Doped Y${}_2$SiO${}_5$
• Complete crystal field calculation of Zeeman-hyperfine splittings in europium
• Laser Site-Selective Spectroscopy and Magnetic Hyperfine Splittings of Ho${}^{3+}$ doped Y${}_2$SiO${}_5$
• Reproduction of the electronic and magnetic structure of the low symmetry sites of Y${}_2$SiO${}_5$ doped with Sm${}^{3+}$ via a parameterized crystal-field model
• Refining spectroscopic calculations for trivalent lanthanide ions: a revised parametric Hamiltonian and open-source solution
• Zeeman-Hyperfine Measurements of a Pseudo-Degenerate Quadruplet in CaF${}_2$:Ho${}^{3+}$
• Infrared Absorption and Laser Spectroscopy of Ho${}^{3+}$ Doped K${}_2$YF${}_5$ Microparticles