Substitutional effects in TiFe for hydrogen storage: a comprehensive review

Abstract

The search for suitable materials for solid-state stationary storage of green hydrogen is pushing the implementation of efficient renewable energy systems. This involves rational design and modification of cheap alloys for effective storage in mild conditions of temperature and pressure. Among many intermetallic compounds described in the literature, TiFe-based systems have recently regained vivid interest as materials for practical applications since they are low-cost and they can be tuned to match required pressure and operation conditions. This work aims to provide a comprehensive review of publications involving chemical substitution in TiFe-based compounds for guiding compound design and materials selection in current and future hydrogen storage applications. Mono- and multi-substituted compounds modify TiFe thermodynamics and are beneficial for many hydrogenation properties. They will be reviewed and deeply discussed, with a focus on manganese substitution.

arXiv comment76 pages, 7 Figures, 5 Tables

References in corpus (1)

• Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound

Cited by in corpus (7)

• High-Entropy Hydrides for Fast and Reversible Hydrogen Storage at Room Temperature: Binding-Energy Engineering via First-Principles Calculations and Experiments
• Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn
• In-situ neutron diffraction during reversible deuterium loading in Ti-rich and Mn-substituted Ti(Fe,Mn)0.90 alloys
• Modeling the thermodynamics of the FeTi hydrogenation under para-equilibrium: an ab-initio and experimental study
• Effect of Niobium Doping on the Crystal Structure and Hydrogen Sorption Properties of TiFe: Combined Synchrotron X-ray Diffraction and Extended X-ray Absorption Fine Structure Study
• An Effective Activation Method for Industrially Produced TiFeMn Powder for Hydrogen Storage
• Microstructural characteristics, atomic-scale features, and growth mechanisms of deuterides (hydrides) in hafnium