On the formation of van der Waals complexes through three-body recombination

Abstract

In this work, we show that van der Waals molecules X-RG (where RG is the rare gas atom) may be created through direct three-body recombination collisions, i.e., X + RG + RG $\to$ X-RG + RG. In particular, the three-body recombination rate at temperatures relevant for buffer gas cell experiments is calculated via a classical trajectory method in hyperspherical coordinates [J. Chem. Phys. 140, 044307 (2014)]. As a result, it is found that the formation of van der Waals molecules in buffer gas cells (1 K $\lesssim T\lesssim 10$ K) is dominated by the long-range tail (distances larger than the LeRoy radius) of the X-RG interaction. For higher temperatures, the short-range region of the potential becomes more significant. Moreover, we notice that the rate of formation of van der Walls molecules is of the same order of magnitude independently of the chemical properties of X. As a consequence, almost any X-RG molecule may be created and observed in a buffer gas cell under proper conditions.

10 pages, 8 figures, submitted to the Journal of Chemical Physics

References in corpus (3)

• Three-body recombination at large scattering lengths in an ultracold atomic gas
• Production of trilobite Rydberg molecule dimers with thousand-Debye permanent electric dipole moments
• Formation of van der Waals molecules in buffer gas cooled magnetic traps

Cited by in corpus (4)

• Classical threshold law for the formation of van der Waals molecules
• Relativistic aspects of orbital and magnetic anisotropies in the chemical bonding and structure of lanthanide molecules
• Ion-atom-atom three-body recombination in cold hydrogen and deuterium plasmas
• Isotope study of the nonlinear pressure shifts of ${}^{85}$Rb and ${}^{87}$Rb hyperfine resonances in Ar, Kr, and Xe buffer gases