Stochastic approach to entropy production in chemical chaos

Abstract

Methods are presented to evaluate the entropy production rate in stochastic reactive systems. These methods are shown to be consistent with known results from nonequilibrium chemical thermodynamics. Moreover, it is proved that the time average of the entropy production rate can be decomposed into the contributions of the cycles obtained from the stoichiometric matrix in both stochastic processes and deterministic systems. These methods are applied to a complex reaction network constructed on the basis of Roessler's reinjection principle and featuring chemical chaos.

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Cited by in corpus (10)

• Nonequilibrium Thermodynamics of Non-Ideal Chemical Reaction Networks
• Macroscopic Stochastic Thermodynamics
• Small-amplitude synchronisation in driven Potts models
• Characterizing the Conditions for Indefinite Growth in Open Chemical Reaction Networks
• Deficiency, Kinetic Invertibility, and Catalysis in Stochastic Chemical Reaction Networks
• Thermodynamics of Growth in Open Chemical Reaction Networks
• Phase coexistence in a weakly stochastic reaction-diffusion system
• Dissipation enables robust extensive scaling of multipartite correlations
• What is a chemostat? Insights from hybrid dynamics and stochastic thermodynamics
• Macroscopic theory of multipartite correlations in permutation-invariant open quantum systems