Stochastic approach to entropy production in chemical chaos

Abstract

Methods are presented to evaluate the entropy production rate in stochastic reactive systems. These methods are shown to be consistent with known results from nonequilibrium chemical thermodynamics. Moreover, it is proved that the time average of the entropy production rate can be decomposed into the contributions of the cycles obtained from the stoichiometric matrix in both stochastic processes and deterministic systems. These methods are applied to a complex reaction network constructed on the basis of Roessler's reinjection principle and featuring chemical chaos.

References in corpus (3)

• Ensemble and Trajectory Thermodynamics: A Brief Introduction
• Irreversible thermodynamics of open chemical networks I: Emergent cycles and broken conservation laws
• Irreversible Circulation of Fluctuation and Entropy Production

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• Dissipation enables robust extensive scaling of multipartite correlations
• What is a chemostat? Insights from hybrid dynamics and stochastic thermodynamics
• Macroscopic theory of multipartite correlations in permutation-invariant open quantum systems