Investigation of potassium-intercalated bulk MoS${}_2$ using transmission electron energy-loss spectroscopy

Abstract

We have investigated the effect of potassium (K) intercalation on $2H$-MoS${}_2$ using transmission electron energy-loss spectroscopy. For K concentrations up to approximately 0.4, the crystals appear to be inhomogeneous with a mix of structural phases and irregular potassium distribution. Above this intercalation level, MoS${}_2$ exhibits a $2a\times 2a$ superstructure in the $ab$ plane and unit cell parameters of a = 3.20 $\unicode{x212B}$ and c = 8.23 $\unicode{x212B}$ indicating a conversion from the $2H$ to the $1T^{\prime }$ or $1T^{\prime \prime }$ polytypes. The diffraction patterns also show a $\sqrt{3}a\times \sqrt{3}a$ and a much weaker $2\sqrt{3}a\times 2\sqrt{3}a$ superstructure that is very likely associated with the ordering of the potassium ions. A semiconductor-to-metal transition occurs signified by the disappearance of the excitonic features from the electron energy-loss spectra and the emergence of a charge carrier plasmon with an unscreened plasmon frequency of 2.78 eV. The plasmon has a positive, quadratic dispersion and appears to be superimposed with an excitation arising from interband transitions. The behavior of the plasmon peak energy positions as a function of potassium concentration shows that potassium stoichiometries of less than $\sim 0.3$ are thermodynamically unstable while higher stoichiometries up to $\sim 0.5$ are thermodynamically stable. Potassium concentrations greater than $\sim 0.5$ lead to the decomposition of MoS${}_2$ and the formation of K${}_2$S. The real part of the dielectric function and the optical conductivity of K${}_{0.41}$MoS${}_2$ were derived from the loss spectra via Kramers-Kronig analysis.

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Cited by in corpus (1)

• Potassium-intercalated bulk HfS${}_2$ and HfSe${}_2$: Phase stability, structure, and electronic structure