paper

Hard and soft x-ray photoemission spectroscopy study of the new Kondo system SmO thin film

arXiv:2004.06315 · doi:10.1103/PhysRevMaterials.4.095001

Abstract

SmO thin film is a new Kondo system showing a resistivity upturn around 10 K and was theoretically proposed to have a topologically nontrivial band structure. We have performed hard x-ray and soft x-ray photoemission spectroscopy to elucidate the electronic structure of SmO. From the Sm 3 core-level spectra, we have estimated the valence of Sm to be 2.96, proving that the Sm has a mixed valence. The valence-band photoemission spectra exhibit a clear Fermi edge originating from the Sm 5-derived band. The present finding is consistent with the theory suggesting a possible topological state in SmO and show that rare-earth monoxides or their heterostructures can be a new playground for the interplay of strong electron correlation and spin-orbit coupling.

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