Geometrical aspects in the analysis of microcanonical phase-transitions
arXiv:2002.06986 · doi:10.3390/e22040380
Abstract
In the present work, we discuss how the functional form of thermodynamic observables can be deduced from the geometric properties of subsets of phase space. The geometric quantities taken into account are mainly extrinsic curvatures of the energy level sets of the Hamiltonian of a system under investigation. In particular, it turns out that peculiar behaviours of thermodynamic observables at a phase transition point are rooted in more fundamental changes of the geometry of the energy level sets in phase space. More specifically, we discuss how microcanonical and geometrical descriptions of phase-transitions are shaped in the special case of models with either nearest-neighbours and mean-field interactions.
References in corpus (27)
- Celestial Mechanics, Conformal Structures, and Gravitational Waves
- A Dynamical Approach to Temperature
- Geometric approach to Hamiltonian dynamics and statistical mechanics
- Inconsistent thermostatistics and negative absolute temperatures
- Geometry of dynamics, Lyapunov exponents and phase transitions
- A Theorem on the origin of Phase Transitions
- Microcanonical entropy inflection points: Key to systematic understanding of transitions in finite systems
- Negative Temperature States in the Discrete Nonlinear Schroedinger Equation
- Geometry of dynamics and phase transitions in classical lattice phi^4 theories
- On the dispute between Boltzmann and Gibbs entropy
- Topology and Phase Transitions II. Theorem on a necessary relation
- Topology and Phase Transitions I. Preliminary Results
- Min-type Morse theory for configuration spaces of hard spheres
- Classification of Phase Transitions by Microcanonical Inflection-Point Analysis
- Computational topology for configuration spaces of hard disks
- Topological Origin of the Phase Transition in a Model of DNA Denaturation
- Topological Description of the Aging Dynamics in Simple Glasses
- Non-analytic microscopic phase transitions and temperature oscillations in the microcanonical ensemble: An exactly solvable 1d-model for evaporation
- Microcanonical Entropy and Dynamical Measure of Temperature for Systems with Two First Integrals
- Phase transitions at high energy vindicate negative microcanonical temperature
- Saddle index properties, singular topology, and its relation to thermodynamical singularities for a phi^4 mean field model
- Topology, phase transitions and the spherical model
- Topological Approach to Microcanonical Thermodynamics and Phase Transition of Interacting Classical Spins
- Microcanonical entropy for classical systems
- Geometric Microcanonical Thermodynamics for Systems with First Integrals
- A microcanonical entropy correcting finite-size effects in small systems
- Microcanonical analysis of a nonequilibrium phase transition
Cited by in corpus (5)
- Evidence for additional third-order transitions in the two-dimensional Ising model
- Stable intermediate phase of secondary structures for semiflexible polymers
- The Geometric Theory of Phase Transitions
- Secondary-Structure Phase Formation for Semifelxible Polymers by Bifurcation in Hyperphase Space
- The precursor of the critical transitions in majority vote model with the noise feedback from the vote layer