Microscopic Origins of the Swim Pressure and the Anomalous Surface Tension of Active Matter
arXiv:1912.11727 · doi:10.1103/PhysRevE.101.012604
Abstract
The unique pressure exerted by active particles -- the "swim" pressure -- has proven to be a useful quantity in explaining many of the seemingly confounding behaviors of active particles. However, its use has also resulted in some puzzling findings including an \textit{extremely negative} surface tension between phase separated active particles. Here, we demonstrate that this contradiction stems from the fact that the swim pressure \textit{is not a true pressure}. At a boundary or interface, the reduction in particle swimming generates a net active force density -- an entirely \textit{self-generated body force}. The pressure at the boundary, which was previously identified as the swim pressure, is in fact an elevated (relative to the bulk) value of the \textit{traditional particle pressure} that is generated by this interfacial force density. Recognizing this unique mechanism for stress generation allows us to define a much more physically plausible surface tension. We clarify the utility of the swim pressure as an "equivalent pressure" (analogous to those defined from electrostatic and gravitational body forces) and the conditions in which this concept can be appropriately applied.
arXiv commentSubmitted June 6, 2019; to appear in Physical Review E. Main text with appendices (8 pages, 6 figures) and Supplemental Material (2 pages, 1 figure). Supplemental videos available upon request or at https://drive.google.com/drive/folders/14Isyut7SRvyrb8PfTwucVcZIPhonh8Ax?usp=sharing
References in corpus (32)
- Motility-Induced Phase Separation
- Athermal Phase Separation of Self-Propelled Particles with no Alignment
- Strong scaling of general-purpose molecular dynamics simulations on GPUs
- How far from equilibrium is active matter?
- Pressure is not a state function for generic active fluids
- Pressure and Phase Equilibria in Interacting Active Brownian Spheres
- Freezing and phase separation of self-propelled disks
- Towards a 'Thermodynamics' of Active Matter
- Irreversibility in active matter systems: Fluctuation theorem and mutual information
- Negative interfacial tension in phase-separated active suspensions
- Generalized Thermodynamics of Phase Equilibria in Scalar Active Matter
- Entropy production in field theories without time reversal symmetry: Quantifying the non-equilibrium character of active matter
- Generalized thermodynamics of Motility-Induced Phase Separation: Phase equilibria, Laplace pressure, and change of ensembles
- Entropy production and fluctuation theorems for active matter
- Hidden entropy production and work fluctuations in an ideal active gas
- Stochastic thermodynamics for active matter
- Anomalous Thermomechanical Properties of a Self-propelled Colloidal Fluid
- Swim pressure on walls with curves and corners
- Ideal bulk pressure of active Brownian particles
- Shape and Displacement Fluctuations in Soft Vesicles Filled by Active Particles
- Heat, temperature and Clausius inequality in a model for active brownian particles
- Chemical potential in active systems: predicting phase equilibrium from bulk equations of state?
- Mechanical pressure and momentum conservation in dry active matter
- Curvature-dependent tension and tangential flows at the interface of motility-induced phases
- Clausius relation for active particles: what can we learn from fluctuations?
- Non-Equilibrium Surface Tension of the Vapour-Liquid Interface of Active Lennard-Jones Particles
- Interface stability, interface fluctuations, and the Gibbs-Thomson relation in motility-induced phase separations
- Current fluctuations of interacting active Brownian particles
- The curved kinetic boundary layer of active matter
- Swimming to Stability: Structural and Dynamical Control via Active Doping
- Statistical Mechanics of Transport Processes in Active Fluids II: Equations of Hydrodynamics for Active Brownian Particles
- Interface height fluctuations and surface tension of driven liquids with time-dependent dynamics
Cited by in corpus (38)
- Phase Diagram of Active Brownian Spheres: Crystallization and the Metastability of Motility-Induced Phase Separation
- Self-Organized Critical Coexistence Phase in Repulsive Active Particles
- Capillary interfacial tension in active phase separation
- Mechanical Theory of Nonequilibrium Coexistence and Motility-Induced Phase Separation
- Dynamical pattern formation without self-attraction in quorum-sensing active matter: the interplay between nonreciprocity and motility
- Entropy production fluctuations encode collective behavior in active matter
- Collective forces in scalar active matter
- Active phase separation: new phenomenology from non-equilibrium physics
- Phase separation and nucleation in mixtures of particles with different temperatures
- Coexistence of active Brownian discs: Van der Waals theory and analytical results
- Inclusions, Boundaries and Disorder in Scalar Active Matter
- Morphological transitions of active Brownian particle aggregates on porous walls
- Polarization-Density Patterns of Active Particles in Motility Gradients
- Designing, Synthesizing and Modeling Active Fluids
- Tuning Nonequilibrium Phase Transitions with Inertia
- Force generation in confined active fluids: The role of microstructure
- Phase separation of active Brownian particles in two dimensions: Anything for a quiet life
- Active interface polarization is a state function
- Theory of Capillary Tension and Interfacial Dynamics of Motility-Induced Phases
- Testing a thermodynamic approach to collective animal behavior in laboratory fish schools
- Interacting particles in an activity landscape
- Kinetic temperature and pressure of an active Tonks gas
- The Mechanics of Nucleation and Growth and the Surface Tensions of Active Matter
- Non-equilibrium coexistence between a fluid and a hotter or colder crystal of granular hard disks
- Dynamic Overlap Concentration Scale of Active Colloids
- Phase Separation, Capillarity, and Odd Surface Flows in Chiral Active Matter
- Theory of Nonequilibrium Multicomponent Coexistence
- Wetting by active fluids
- Quantifying the non-equilibrium activity of an active colloid
- Active doping controls the mode of failure in dense colloidal gels
- Theory for the Anomalous Phase Behavior of Inertial Active Brownian Particles
- Dynamics and rupture of doped Motility Induced Phase Peparation
- Effective interactions in active Brownian particles
- Active osmotic-like pressure on permeable inclusions
- Wetting transition of active Brownian particles on a thin membrane
- An Infinite Set of Integral Formulae for Polar, Nematic, and Higher Order Structures at the Interface of Motility-Induced Phase Separation
- Critical Motility-Induced Phase Separation in Three Dimensions is Consistent with Ising Universality
- Virial stress in systems of active Brownian particles in the presence of translational and rotational inertia