Nanoparticulate Metal Oxide Top Electrode Interface Modification Improves the Thermal Stability of Inverted Perovskite Photovoltaics

Abstract

Solution processed γ-Fe2O3 nanoparticles via the solvothermal colloidal synthesis in conjunction with ligand-exchange method are used for interface modification of the top electrode in inverted perovskite solar cells. In comparison to more conventional top electrodes such as PC(70)BM/Al and PC(70)BM/AZO/Al, we show that incorporation of a γ-Fe2O3 provides an alternative solution processed top electrode (PC(70)BM/γ-Fe2O3/Al) that not only results in comparable power conversion efficiencies but also improved thermal stability of inverted perovskite photovoltaics. The origin of improved stability of inverted perovskite solar cells incorporating PC(70)BM/ γ-Fe2O3/Al under accelerated heat lifetime conditions is attributed to the acidic surface nature of γ-Fe2O3 and reduced charge trapped density within PC(70)BM/ γ-Fe2O3/Al top electrode interfaces.

24 pages, 11 figures

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Cited by in corpus (4)

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• Nitrobenzene as Additive to Improve Reproducibility and Degradation Resistance of Highly Efficient Methylammonium-Free Inverted Perovskite Solar Cells
• Surface Treatment of Cu:NiOx Hole-Transporting Layer Using \b{eta}-Alanine for Hysteresis-Free and Thermally Stable Inverted Perovskite Solar Cells