Gradient dynamics model for drops spreading on polymer brushes

Abstract

When a liquid drop spreads on an adaptive substrate the latter changes its properties what may result in an intricate coupled dynamics of drop and substrate. Here we present a generic mesoscale hydrodynamic model for such processes that is written as a gradient dynamics on an underlying energy functional. We specify the model details for the example of a drop spreading on a dry polymer brush. There, liquid absorption into the brush results in swelling of the brush causing changes in the brush topography and wettability. The liquid may also advance within the brush via diffusion (or wicking) resulting in coupled drop and brush dynamics. The specific model accounts for coupled spreading, absorption and wicking dynamics when the underlying energy functional incorporates capillarity, wettability and brush energy. After employing a simple version of such a model to numerically simulate a droplet spreading on a swelling brush we conclude with a discussion of possible model extensions.

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• Sessile drop evaporation in a gap -- crossover between diffusion-limited and phase transition-limited regime
• Soft wetting with (a)symmetric Shuttleworth effect
• Drops on polymer brushes -- advances in thin-film modelling of adaptive substrates
• Non-equilibrium configurations of swelling polymer brush layers induced by spreading drops of weakly volatile oil
• Stick-slip Dynamics in the Forced Wetting of Polymer Brushes
• Controlling the dewetting morphologies of thin liquid films by switchable substrates
• Gradient dynamics approach to reactive thin-film hydrodynamics
• Drops of volatile binary mixtures on brush-covered substrates
• A geometry-based model for spreading drops applied to drops on a silicon wafer and a swellable polymer brush film