Unusual Valence State in the Antiperovskites Sr${}_3$SnO and Sr${}_3$PbO Revealed by X-ray Photoelectron Spectroscopy

Abstract

The class of antiperovskite compounds $A_{3}B$O ($A$ = Ca, Sr, Ba; $B$ = Sn, Pb) has attracted interest as a candidate 3D Dirac system with topological surface states protected by crystal symmetry. A key factor underlying the rich electronic structure of $A_{3}B$O is the unusual valence state of $B$, i.e., a formal oxidation state of $-4$. Practically, it is not obvious whether anionic $B$ can be stabilized in thin films, due to its unusual chemistry, as well as the polar surface of $A_{3}B$O, which may render the growth-front surface unstable. We report X-ray photoelectron spectroscopy (XPS) measurements of single-crystalline films of Sr${}_3$SnO and Sr${}_3$PbO grown by molecular beam epitaxy (MBE). We observe shifts in the core-level binding energies that originate from anionic Sn and Pb, consistent with density functional theory (DFT) calculations. Near the surface, we observe additional signatures of neutral or cationic Sn and Pb, which may point to an electronic or atomic reconstruction with possible impact on putative topological surface states.

arXiv comment8 pages, 6 figures

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Cited by in corpus (5)

• Robust weak antilocalization due to spin-orbital entanglement in Dirac material Sr${}_3$SnO
• Higher-order topological insulators in antiperovskites
• Planar Hall effect with sixfold oscillations in a Dirac antiperovskite
• Anionic nickel and nitrogen effects in the chiral antiferromagnetic antiperovskite Mn${}_3$NiN
• Perspective: Molecular beam epitaxy of antiperovskite oxides