Investigating the Efficiency of Explosion Chemistry as a Source of Complex Organic Molecules in TMC-1
arXiv:1905.01901 · doi:10.3847/1538-4357/ab1f7b
Abstract
Many species of complex organic molecules (COMs) have been observed in several astrophysical environments but it is not clear how they are produced, particularly in cold, quiescent regions. One process that has been proposed as a means to enhance the chemical complexity of the gas phase in such regions is the explosion of the ice mantles of dust grains. In this process, a build up of chemical energy in the ice is released, sublimating the ices and producing a short lived phase of high density, high temperature gas. The gas-grain chemical code UCLCHEM has been modified to treat these explosions in order to model the observed abundances of COMs towards the TMC-1 region. It is found that, based on our current understanding of the explosion mechanism and chemical pathways, the inclusion of explosions in chemical models is not warranted at this time. Explosions are not shown to improve the model's match to the observed abundances of simple species in TMC-1. Further, neither the inclusion of surface diffusion chemistry, nor explosions, results in the production of COMs with observationally inferred abundances.
arXiv commentAccepted for publication in ApJ
References in corpus (30)
- The chemical composition of the Sun
- The UMIST database for astrochemistry 2012
- Formation of methyl formate and other organic species in the warm-up phase of hot molecular cores
- Gas and grain chemical composition in cold cores as predicted by the Nautilus 3-phase model
- Chemistry of Dark Clouds: Databases, Networks, and Models
- Formation of complex organic molecules in cold objects: the role of gas phase reactions
- Formation of Complex Molecules in Prestellar Cores: a Multilayer Approach
- H-atom addition and abstraction reactions in mixed CO, H2CO and CH3OH ices: an extended view on complex organic molecule formation
- On the reservoir of sulphur in dark clouds : chemistry and elemental abundance reconciled
- Dust as interstellar catalyst I. Quantifying the chemical desorption process
- Exploring Molecular Complexity with ALMA (EMoCA): Deuterated complex organic molecules in Sagittarius B2(N2)
- Discovery of Interstellar Propylene (CH_2CHCH_3): Missing Links in Interstellar Gas-Phase Chemistry
- The effect of uncertainties on chemical models of dark clouds
- Seeds Of Life In Space (SOLIS): The organic composition diversity at 300--1000 au scale in Solar-type star forming regions
- The genealogical tree of ethanol: gas-phase formation of glycolaldehyde, acetic acid and formic acid
- UCLCHEM: A Gas-Grain Chemical Code
- Seeds of Life in Space (SOLIS) III. Formamide in protostellar shocks: evidence for gas-phase formation
- Desorption From Interstellar Ices
- Formation and recondensation of complex organic molecules during protostellar luminosity outbursts
- On Cosmic Ray-Driven Grain Chemistry in Cold Core Models
- Gas-grain chemistry in cold interstellar cloud cores with a microscopic Monte Carlo approach to surface chemistry
- Chemical modelling of complex organic molecules with peptide-like bonds in star-forming regions
- Episodic Explosions in Interstellar Ices
- Excitation of the aromatic infrared emission bands: Chemical energy in hydrogenated amorphous carbon particles?
- Chemical modelling of glycolaldehyde and ethylene glycol in star-forming regions
- Dust Motions in Magnetized Turbulence: Source of Chemical Complexity
- A radical route to interstellar propylene formation
- A study of methanol and silicon monoxide production through episodic explosions of grain mantles in the Central Molecular Zone
- Statistical study of uncertainties in the diffusion rate of species on interstellar ice and its impact on chemical model predictions
- Chemistry in Evaporating Ices: Unexplored Territory