Minimal constraints for Maximum Caliber analysis of dissipative steady state systems

Abstract

Maximum Caliber (Max Cal) is purported to be a general variational principle for Non-Equilibrium Statistical Physics (NESP). But recently, Jack and Evans and Maes have raised concerns about how Max Cal handles dissipative processes. Here, we show that the problem does not lie in Max Cal; the problem is in the use of insufficient constraints. We also present an exactly solvable single-particle model of dissipation, valid far from equilibrium, and its solution by Maximum Caliber. The model illustrates how the influx and efflux of work and heat into a flowing system alters the distribution of trajectories. Maximum Caliber is a viable principle for dissipative systems.

References in corpus (5)

• A nonequilibrium equality for free energy differences
• The Entropy Production Fluctuation Theorem and the Nonequilibrium Work Relation for Free Energy Differences
• Maximum Caliber: a general variational principle for dynamical systems
• Maximum caliber is a general variational principle for nonequilibrium statistical mechanics
• Absence of dissipation in trajectory ensembles biased by currents

Cited by in corpus (3)

• Microscopic reweighting for non-equilibrium steady states dynamics
• Reweighting non-equilibrium steady-state dynamics along collective variables
• Probabilistic and Maximum Entropy Modeling of Chemical Reaction Systems: Characteristics and Comparisons to Mass Action Kinetic Models