Superconductivity in a new hexagonal high entropy alloy

Sourav Marik; Kapil Motla; Maneesha Varghese; K. P. Sajilesh; Deepak Singh; Y. Breard; P. Boullay; R. P. Singh

doi:10.1103/PhysRevMaterials.3.060602

paper

Superconductivity in a new hexagonal high entropy alloy

arXiv:1904.06203 · doi:10.1103/PhysRevMaterials.3.060602

Abstract

High entropy alloys (HEAs) are the new class of materials with an attractive combination of tunable mechanical and physicochemical properties. They crystallize mainly in cubic structures, however, for practical applications, HEAs with hexagonal close-packed (hcp) structure are highly desirable in connection to their in general high hardness. Herein, we report the synthesis, structure and detailed superconducting properties of Re $_{0.56}$ Nb $_{0.11}$ Ti $_{0.11}$ Zr $_{0.11}$ Hf $_{0.11}$ -the first hexagonal superconducting high entropy alloy (HEA) composed of five randomly distributed transition-metals. Combination of room temperature precession electron diffraction, precession electron diffraction tomography and powder X-ray diffraction is utilized to determine the room temperature crystal structure. Transport, magnetic and heat capacity measurements show that the material is a type-II superconductor with the bulk superconducting transition at $T_{c}$ = 4.4 K, lower critical field $H_{c 1}$ (0) = 2.3 mT and upper critical field $H_{c 2}$ (0) = 3.6 T. Low-temperature specific heat measurement indicates that Re $_{0.56}$ Nb $_{0.11}$ Ti $_{0.11}$ Zr $_{0.11}$ Hf $_{0.11}$ is a phonon-mediated superconductor in the weak electron-phonon coupling limit with a normalized specific heat jump $\frac{Δ C _{e l}}{γ _{n} T _{c}}$ = 1.32. Further, hexagonal to cubic structural transition is observed by lowering the valence electron counts and $T_{c}$ follows crystalline-like behaviour.

6 Pages, 9 Figures. arXiv admin note: text overlap with arXiv:1804.10092

Superconductivity in a new hexagonal high entropy alloy

Abstract

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