Comment on "Experimental Evidence for a State-Point-Dependent Density-Scaling Exponent of Liquid Dynamics"

Abstract

Recently Sanz et al. [A. Sanz, T. Hecksher, H.W. Hansen, J.C. Dyre, K. Niss, and U.R. Pedersen, Phys. Rev. Lett. 122, 055501 (2019).] reported that the scaling exponent gamma for tetramethyl-tetraphenyl-trisiloxane (DC704) varied with temperature; i.e., was not a material constant. Such a finding is at odds with previously published results on this compound and on more than 100 other liquids and polymers. The result of Sanz et al. comes from their measurement of a pressure dependence of the relaxation time at low temperature that becomes weaker with increasing pressure. Such a result is unphysical and contrary to the behavior of all known liquids. We re-measured this pressure dependence for DC704 and find it to be linear over the studied range. Thus, the conclusion of Sans et al. is incorrect; gamma for DC704 is state-point independent, in accord with other simple liquids and polymers.

arXiv comment2 pages, 2 figures

References in corpus (3)

• Hidden scale invariance in molecular van der Waals liquids: A simulation study
• Density scaling as a property of strongly correlating viscous liquids
• Experimental evidence of a state-point dependent scaling exponent of liquid dynamics

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