Langevin Approach to Quantum Optics with Molecules

Abstract

We investigate the interaction between light and molecular systems modeled as quantum emitters coupled to a multitude of vibrational modes via a Holstein-type interaction. We follow a quantum Langevin equations approach that allows for analytical derivations of absorption and fluorescence profiles of molecules driven by classical fields or coupled to quantized optical modes. We retrieve analytical expressions for the modification of the radiative emission branching ratio in the Purcell regime and for the asymmetric cavity transmission associated with dissipative cross-talk between upper and lower polaritons in the strong coupling regime. We also characterize the Förster resonance energy transfer process between donor-acceptor molecules mediated by the vacuum or by a cavity mode.

References in corpus (24)

• The photon blockade effect in optomechanical systems
• Conductivity in organic semiconductors hybridized with the vacuum field
• Cavity-controlled chemistry in molecular ensembles
• Atoms and Molecules in Cavities: From Weak to Strong Coupling in QED Chemistry
• Ground-state cooling of a micromechanical oscillator: generalized framework for cold damping and cavity-assisted cooling schemes
• Single-photon Optomechanics
• Extraordinary exciton conductance induced by strong coupling
• Suppressing photochemical reactions with quantized light fields
• Cavity enhanced transport of excitons
• Cavity Born-Oppenheimer Approximation for Correlated Electron-Nuclear-Photon Systems
• Cavity-enhanced transport of charge
• Turning a molecule into a coherent two-level quantum system
• Dark Vibronic Polaritons and the Spectroscopy of Organic Microcavities
• Theory of Nanoscale Organic Cavities: The Essential Role of Vibration-Photon Dressed States
• Can ultrastrong coupling change ground state chemical reactions?
• Tensor network simulation of non-Markovian dynamics in organic polaritons
• Exact states and spectra of vibrationally dressed polaritons
• Origin of the asymmetric light emission from molecular exciton-polaritons
• Cavity-assisted mesoscopic transport of fermions: Coherent and dissipative dynamics
• Non-markovian polariton dynamics in organic strong coupling
• Spontaneous emission spectrum of a two-level atom in a very high Q cavity
• Energy transfer and correlations in cavity-embedded donor-acceptor configurations
• Enhanced collective Purcell effect of coupled quantum emitter systems
• Cavity-controlled ultracold chemistry

Cited by in corpus (48)

• Molecular polaritons for controlling chemistry with quantum optics
• Cooperative quantum phenomena in light-matter platforms
• A perspective on ab initio modeling of polaritonic chemistry: The role of non-equilibrium effects and quantum collectivity
• Polaritonic Coupled-Cluster Theory
• Cavity-modulated ionization potentials and electron affinities from quantum electrodynamics coupled-cluster theory
• Benchmarking Semiclassical and Perturbative Methods for Real-time Simulations of Cavity-Bound Emission and Interference
• Phonon-induced optical dephasing in single organic molecules
• Equation-of-motion cavity quantum electrodynamics coupled-cluster theory for electron attachment
• Disorder enhanced vibrational entanglement and dynamics in polaritonic chemistry
• Reduced Density-Matrix Approach to Strong Matter-Photon Interaction
• Maxwell's lesser demon: a quantum engine driven by pointer measurements
• Light-matter hybrid-orbital-based first-principles methods: the influence of the polariton statistics
• The Ising model in a light-induced quantized transverse field
• A quantum optics approach to photoinduced electron transfer in cavities
• Molecular polaritonics in dense mesoscopic disordered ensembles
• Molecule-photon interactions in phononic environments
• When do molecular polaritons behave like optical filters?
• Hybrid superconductor-semiconductor systems for quantum technology
• Plasmonic Purcell Effect in Organic Molecules
• Collective Polaritonic Effects on Chemical Dynamics Suppressed by Disorder
• Multidimensional Coherent Spectroscopy of Molecular Polaritons: Langevin Approach
• Nanocavities for Molecular Optomechanics: their fundamental description and applications
• Engineering long-lived vibrational states for an organic molecule
• Probing Light-Induced Conical Intersections by Monitoring Multidimensional Polaritonic Surfaces
• Generalized input-output method: A new route to quantum transport junctions
• Crafting the dynamical structure of synchronization by harnessing bosonic multilevel cavity QED
• Theory for the stationary polariton response in the presence of vibrations
• Nonadditive Enhancement of Nonequilibrium Atom-Surface Interactions
• Generation of macroscopic entangled cat states in a molecular cavity-QED system
• Cooperative subwavelength molecular quantum emitter arrays
• Quantum Thermometry with a Dissipative Quantum Rabi System
• Enantio-detection via cavity-assisted three-photon processes
• Adiabatic elimination for ensembles of emitters in cavities with dissipative couplings
• Classical and quantum light-induced non-adiabaticity in molecular systems
• Floquet engineering of molecular dynamics via infrared coupling
• Impact of Cavity on Molecular Ionization Spectra
• Understanding polaritonic chemistry from ab initio quantum electrodynamics
• Polariton response in the presence of Brownian dissipation from molecular vibrations
• Thermalization rate of polaritons in strongly-coupled molecular systems
• Scaling law for Kasha's rule in photoexcited molecular aggregates
• Nonreciprocal Quantum Sensing
• Cascade Brillouin scattering as a mechanism for photoluminescence from rough surfaces of noble metals
• Practical guide to the statistical mechanics of molecular polaritons
• Nonlinear opto-vibronics in molecular systems
• Quantum estimation of tripartite coupling in Spin-Magnon-Mechanical Hybrid Systems
• Indirect probing of light-induced nonadiabatic dynamics in lossy nanocavities
• Collective Effects of Organic Molecules based on Holstein-Tavis-Cummings Model
• Exceptional point in self-consistent Markovian master equations