Non-markovian polariton dynamics in organic strong coupling
arXiv:1307.8378 · doi:10.1140/epjd/e2014-50539-x
Abstract
Strongly coupled organic systems are characterized by unusually large Rabi splittings, even in the vacuum state. They show the counter-intuitive feature of a lifetime of the lower polariton state longer than for all other excited states. Here we build up a new theoretical framework to understand the dynamics of such coupled system. In particular, we show that the non-Markovian character of the relaxation of the dressed organic system explains the long lifetime of the lower polariton state.
Expanded version: 6 pages, 4 figures
References in corpus (2)
Cited by in corpus (15)
- Cavity-induced modifications of molecular structure in the strong coupling regime
- Multiple Rabi Splittings under Ultra-Strong Vibrational Coupling
- Quantum theory of collective strong coupling of molecular vibrations with a microcavity mode
- Langevin Approach to Quantum Optics with Molecules
- Quantum-Electrodynamical Time-Dependent Density Functional Theory. I. A Gaussian Atomic Basis Implementation
- Origin of the asymmetric light emission from molecular exciton-polaritons
- Femtosecond Photophysics of Molecular Polaritons
- Towards strongly correlated photons in arrays of dissipative nonlinear cavities under a frequency-dependent incoherent pumping
- Charge-Transfer Chemical Reactions in Nanofluidic Fabry-P{é}rot Cavities
- Collective Rayleigh Scattering from Molecular Ensembles under Strong Coupling
- First principles modeling of exciton-polaritons in polydiacetylene chains
- Adiabatic elimination for ensembles of emitters in cavities with dissipative couplings
- Precise determination of excitation energies in condensed-phase molecular systems based on exciton-polariton measurements
- Quantum Light from a Metal Nanoparticle
- Direct readout of excited state lifetimes in chlorin chromophores under electronic strong coupling