Lattice vibrations and dynamic disorder in two-dimensional hybrid lead-halide perovskites
arXiv:1812.05255
Abstract
By means of non-resonant Raman spectroscopy and density functional theory calculations, we measure and assign the vibrational spectrum of two distinct two-dimensional lead-iodide perovskite derivatives. These two samples are selected in order to probe the effects of the organic cation on lattice dynamics. One templating cation is composed of a phenyl-substituted ammonium derivative, while the other contains a linear alkyl group. We find that modes that directly involve the organic cation are more prevalent in the phenyl-substituted derivative. Comparison of the temperature dependence of the Raman spectra reveals differences in the nature of dynamic disorder, with a strong dependence on the molecular nature of the organic moiety.
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