Graph similarity drives zeolite diffusionless transformations and intergrowth

Abstract

Predicting and directing polymorphic transformations is a critical challenge in zeolite synthesis. Although interzeolite transformations enable selective crystallization, their design lacks predictions to connect framework similarity and experimental observations. Here, computational and theoretical tools are combined to data-mine, analyze and explain interzeolite relations. It is observed that building units are weak predictors of topology interconversion and insufficient to explain intergrowth. By introducing a supercell-invariant metric that compares crystal structures using graph theory, we show that topotactic and reconstructive (diffusionless) transformations occur only between graph-similar pairs. Furthermore, all known instances of intergrowth occur between either structurally-similar or graph-similar frameworks. Backed with exhaustive literature results, we identify promising pairs for realizing novel diffusionless transformations and intergrowth. Hundreds of low-distance pairs are identified among known zeolites, and thousands of hypothetical frameworks are connected to known zeolites counterparts. The theory opens a venue to understand and control zeolite polymorphism.

arXiv commentPre-peer review manuscript; 8 pages, 3 figures

References in corpus (3)

• Crystal Graph Convolutional Neural Networks for an Accurate and Interpretable Prediction of Material Properties
• On representing chemical environments
• Comparing molecules and solids across structural and alchemical space

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