Charge Fluctuations in the NdO${}_{1-x}$F${}_x$BiS${}_2$ Superconductors

Abstract

The local atomic structure of superconducting NdO${}_{1-x}$F${}_x$BiS${}_2$ ($x$=0.2 and 0.4) is investigated using neutron diffraction and the pair density function analysis technique. In the non-superconducting $x$=0.2 composition, ferrodistortive displacements of the pyramidal sulfur ions break the tetragonal symmetry and a superlattice structure emerges with peaks appearing at $h+k$ odd reflections superimposed on the even reflections of the $P4/nmm$ symmetry. In the superconducting $x$=0.4 composition, similar ferrodistortive displacements are observed but with different magnitudes coupled with in-plane Bi distortions. The distortions are indicative of charge fluctuations that may lead to charge localization and suppression of superconductivity.

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• SnAs-based layered superconductor NaSn2As2
• Evolution of Anisotropic Displacement Parameters and Superconductivity with Chemical Pressure in BiS2-Based REO0.5F0.5BiS2 (RE = La, Ce, Pr, and Nd)
• Direct Observation of an Incommensurate Charge Density Wave in the BiS2-based Superconductor NdO1-xFxBiS2
• Pressure-induced superconductivity in layered pnictogen diselenide NdO${}_{0.8}$F${}_{0.2}$Sb${}_{1-x}$Bi${}_x$Se${}_2$ (x = 0.3 and 0.7)
• Investigation of in-plane anisotropy of c-axis magnetoresistance for BiCh2-based layered superconductor NdO0.7F0.3BiS2
• Crystal Structure and Thermoelectric Transport Properties of As-Doped Layered Pnictogen Oxyselenides NdO0.8F0.2Sb1-xAsxSe2