Theoretical analysis of effective electric fields in mercury monohalides

Abstract

Mercury monohalides are promising candidates for electron electric dipole moment searches. This is due to their extremely large values of effective electric fields, besides other attractive experimental features. We have elucidated the theoretical reasons of our previous work. We have also presented a detailed analysis of our calculations, by including the most important of the correlation effects' contributions. We have also analyzed the major contributions to the effective electric field, at the Dirac- Fock level, and identified those atomic orbitals' mixings that contribute significantly to it.

References in corpus (6)

• Candidate molecular ions for an electron electric dipole moment experiment
• Prospects for an electron electric dipole moment search in metastable ThO and ThF${}^{+}$
• Application of a Relativistic Coupled-Cluster Theory to the Effective Electric Field in YbF
• Mercury Monohalides: Suitability for Electron Electric Dipole Moment Searches
• Electron EDM as a Sensitive Probe of PeV Scale Physics
• Permanent Electric Dipole Moment of Strontium Monofluoride as a Test of the Accuracy of a Relativistic Coupled Cluster Method

Cited by in corpus (2)

• Enhanced sensitivity of the electron electric dipole moment from YbOH: The role of theory
• Towards CP Violation Studies on Superheavy Molecules: Theoretical and Experimental Perspective