Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water

Abstract

Using porous electrodes containing nickel hexacyanoferrate (NiHCF) nanoparticles, we construct and test a device for capacitive deionization in a two flow-channel device where the intercalation electrodes are in direct contact with an anion-exchange membrane. Upon negatively charging NiHCF, cations intercalate into it and the water in its vicinity is desalinated; at the same time water in the opposing electrode becomes more saline upon positively charging the NiHCF in that electrode. In a cyclic process of charge and discharge, fresh water is continuously produced, alternating between the two channels in sync with the direction of applied current. We present proof-of-principle experiments of this technology for single salt solutions, where we analyze various levels of current and cycle durations. We analyze salt removal rate and energy consumption. In desalination experiments with salt mixtures we find a threefold enhancement for K${}^{+}$ over Na${}^{+}$-adsorption, which shows the potential of NiHCF intercalation electrodes for selective ion separation from mixed ionic solutions.

References in corpus (2)

• Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water
• Activated carbon is an electron-conducting amphoteric ion adsorbent

Cited by in corpus (10)

• Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water
• Performance Metrics for the Objective Assessment of Capacitive Deionization Systems
• Electrochemical Ion Insertion: From Atoms to Devices
• Size-based ion selectivity of micropore electric double layers in capacitive deionization electrodes
• The difference between Faradaic and non-Faradaic electrode processes
• Embedded, micro-interdigitated flow fields in high areal-loading intercalation electrodes towards seawater desalination and beyond
• Equivalent circuit model for electrosorption with redox active materials
• Theory of water desalination with intercalation materials
• Quantifying the Trade-offs between Energy Consumption and Salt Removal Rate in Membrane-free Cation Intercalation Desalination
• Theory of Faradaically Modulated Redox Active Electrodes for Electrochemically Mediated Selective Adsorption Processes