Ultralong-range triatomic Rydberg molecules in an electric field
arXiv:1601.05049 · doi:10.1088/0953-4075/49/12/124002
Abstract
We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the -wave and -wave interactions we perform electronic structure calculations and analyze the adiabatic electronic potentials evolving from the Rb Rydberg degenerate manifold. We hereby focus on three different classes of geometries of the Rydberg molecules, including symmetric, asymmetric and planar configurations. The metamorphosis of these potential energy surfaces in the presence of an external electric field is explored.
8 pages, 8 figures
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- Stretching and bending dynamics in triatomic ultralong-range Rydberg molecules
- The building principle of triatomic trilobite Rydberg molecules
- Breaking and trapping Cooper pairs by Rydberg-molecule spectroscopy in atomic Fermi superfluids
- A Green's function approach to giant-dipole systems