New intercalation superconductor Lix(C6H16N2)yFe2-zSe2 with a very large interlayer-spacing and Tc = 38 K

S. Hosono; T. Noji; T. Hatakeda; T. Kawamata; M. Kato; Y. Koike

doi:10.7566/JPSJ.83.113704

paper

New intercalation superconductor Lix(C6H16N2)yFe2-zSe2 with a very large interlayer-spacing and Tc = 38 K

arXiv:1510.08625 · doi:10.7566/JPSJ.83.113704

Abstract

A new iron-based superconductor, Lix(C6H16N2)yFe2-zSe2, with Tc = 38 K has successfully been synthesized via the intercalation of lithium and hexamethylenediamine into FeSe. The superconducting transition has been confirmed not only by magnetic susceptibility measurements but also by electrical resistivity ones. The interlayer spacing, namely, the dicstance between neighboring Fe layers, d, is 16.225(5) $A ˚$ , which is the largest among those of FeSe-based intercalation compounds. It has been found that the dependence of Tc on d in FeSe-based intercalation superconductors appears domic.

arXiv comment10 pages, 5 figures

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