paper

The Gibbs paradox revisited from the fluctuation theorem with absolute irreversibility

arXiv:1506.04468 · doi:10.1103/PhysRevLett.118.060601

Abstract

The inclusion of the factor in the thermodynamic entropy proposed by Gibbs is shown to be equivalent to the validity of the fluctuation theorem with absolute irreversibility for gas mixing.

5 pages, 2 figures