From single-shot towards general work extraction in a quantum thermodynamic framework

Abstract

This paper considers work extraction from a quantum system to a work storage system (or weight) following reference [1]. An alternative approach is here developed that relies on the comparison of subspace dimensions without a need to introduce thermo-majorisation used previously. Optimal single shot work for processes where a weight transfers from (a) a single energy level to another single energy level is then re-derived. In addition we discuss the final state of the system after work extraction and show that the system typically ends in its thermal state, while there are cases where the system is only close to it. The work of formation in the single level transfer setting [1] is also re-derived. The approach presented now allows the extension of the single shot work concept to work extraction (b) involving multiple final levels of the weight. A key conclusion here is that the single shot work for case (a) is appropriate only when a \emph{resonance} of a particular energy is required. When wishing to identify "work extraction" with finding the weight in a specific available energy or any higher energy a broadening of the single shot work concept is required. As a final contribution we consider transformations of the system that (c) result in general weight state transfers. Introducing a transfer-quantity allows us to formulate minimum requirements for transformations to be at all possible in a thermodynamic framework. We show that choosing the free energy difference of the weight as the transfer-quantity one recovers various single shot results including single level transitions (a), multiple final level transitions (b), and recent results on restricted sets of multi-level to multi-level weight transfers.

3 figures, added a discussion of bringing in new baths, minor changes throughout, accepted in NJP

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• Fluctuation theorems: Work is not an observable
• Description of quantum coherence in thermodynamic processes requires constraints beyond free energy
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• Typicality for Generalized Microcanonical Ensembles
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