Inter-band Coulomb coupling in narrow gap semiconductor nanocrystals: $\mathbf{k}\cdot \mathbf{p}$ theory

Abstract

We derive the matrix elements of Coulomb interaction between states with different number of electrons and holes in a semiconductor nanocrystal within the 8-band $\mathbf{k}\cdot \mathbf{p}$ theory. These matrix elements are responsible for multiple exciton generation which may contribute to the enhancement of the efficiency of solar cells. Our calculations are performed within the multi band envelope function formalism based on the states resulting from diagonalization of the 8-band $\mathbf{k}\cdot \mathbf{p}$ Hamiltonian. We study in detail and compare two contributions to the inter-band Coulomb coupling: the mesoscopic one, which involves only the envelope functions and relies on band mixing, and the microscopic one, that relies on the Bloch parts of the wave functions and is non-zero even between single- band states. We show that these two contributions are of a similar order of magnitude. We study also the statistical distribution of the magnitudes of the inter-band Coulomb matrix elements and show that the overall coupling to remote states decays according to a power law favorable for the convergence of numerical computations.

arXiv comment8 pages, 5 figures; minor corrections with respect to v2

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Cited by in corpus (3)

• Controlled Coherent Coupling in a Quantum Dot Molecule Revealed by Ultrafast Four-Wave Mixing Spectroscopy
• Quenching of exciton recombination in strained two-dimensional monochalcogenides
• Efficiency of the coherent biexciton admixture mechanism for multiple exciton generation in InAs nanocrystals