An Energetic Variational Approach for ion transport
arXiv:1408.4114 · doi:10.4310/CMS.2014.v12.n4.a9
Abstract
The transport and distribution of charged particles are crucial in the study of many physical and biological problems. In this paper, we employ an Energy Variational Approach to derive the coupled Poisson-Nernst-Planck-Navier-Stokes system. All physics is included in the choices of corresponding energy law and kinematic transport of particles. The variational derivations give the coupled force balance equations in a unique and deterministic fashion. We also discuss the situations with different types of boundary conditions. Finally, we show that the Onsager's relation holds for the electrokinetics, near the initial time of a step function applied field.
References in corpus (1)
Cited by in corpus (5)
- Dynamics of Current, Charge and Mass
- Transport of Charged Particles: Entropy Production and Maximum Dissipation Principle
- A Modified Poisson--Nernst--Planck Model with Excluded Volume Effect: Theory and Numerical Implementation
- Analysis of the Mean Field Free Energy Functional of Electrolyte Solution with Non-zero Boundary Conditions and the Generalized PB/PNP Equations with Inhomogeneous Dielectric Permittivity
- Global Existence of the Non-isothermal Poisson-Nernst-Planck-Fourier System