paper

Optimizing entropy bounds for macroscopic systems

arXiv:1404.1802 · doi:10.1103/PhysRevE.89.052137

Abstract

The universal bound on specific entropy was originally inferred from black hole thermodynamics. We here show from classical thermodynamics alone that for a system at fixed volume or fixed pressure, the ratio of entropy to nonrelativistic energy has a unique maximum . A simple argument from quantum dynamics allows one to set a model--independent upper bound on which is usually much tighter than the universal bound. We illustrate with two examples.

13 pages, 2 figures, LaTeX

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