Attosecond streaking of Cohen-Fano interferences in the photoionization of H${}_2^{+}$

Abstract

We present the first numerical simulation of the time delay in the photoionization of the simplest diatomic molecule H${}_2^{+}$ as observed by attosecond streaking. We show that the strong variation of the Eisenbud-Wigner-Smith time delay as a function of energy and emission angle becomes observable in the streaking time shift provided laser field-induced components are accounted for. The strongly enhanced photoemission time shifts are traced to destructive Cohen-Fano (or two-center) interferences. Signatures of these interferences in the streaking trace are shown to be enhanced when the ionic fragments are detected in coincidence.