Engineering an all-optical route to ultracold molecules in their vibronic ground state

Abstract

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is achieved by short laser pulses in a Raman-like pump-dump process where an additional near-infrared laser field couples the excited state to an auxiliary state. The coupling due to the additional field effectively changes the shape of the excited state potential and allows for efficient population transfer to low-lying vibrational levels of the electronic ground state. Repetition of many pump-dump sequences together with collisional relaxation allows for accumulation of molecules in v=0.

Phys. Rev. A, in press

References in corpus (4)

• Precision Test of Mass Ratio Variations with Lattice-Confined Ultracold Molecules
• Stabilization of Ultracold Molecules Using Optimal Control Theory
• Making ultracold molecules in a two color pump-dump photoassociation scheme using chirped pulses
• Enhancement of the formation of ultracold ${}^{85}$Rb${}_2$ molecules due to resonant coupling