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Infrared Spectroscopy and Photochemistry of Aromatic Nitriles in Para-Hydrogen Matrices
Sam McGrath, Vincent J. Esposito, Linshan Zeng +6
Motivated by recent detections of several aromatic nitriles in Taurus Molecular Cloud-1, we report laboratory and theoretical investigations of the vibrational spectroscopy and pho…
Exploring the Limits of Spectral Line Stacking in Spectral Line Data and Application Toward the Detection of Bulk C Enrichment of Aromatics in TMC-1
Miya Duffy, Ryan A. Loomis, Martin S. Holdren +9
The formation history of polycyclic aromatic hydrocarbons (PAHs) in the interstellar medium remains a topic of active debate, with proposed mechanisms ranging from high-temperature…
Detection of the Polycyclic Aromatic Hydrocarbon Phenalene (CH) in the Very Low Luminosity Object (VeLLO) MC27/L1521F
Gabi Wenzel, Thomas H. Speak, Ci Xue +12
To date, 14 polycyclic aromatic hydrocarbons (PAHs) ranging in size from two to seven (including five- and six-membered) carbon rings have been detected in the starless dense core…
The impact of hydrogen atom tunneling on aromatic chemistry in TMC-1
Reace H. J. Willis, Thomas H. Speak, Alex N. Byrne +2
Hydrogen atom tunneling likely plays a substantial role in the gas-phase chemistry of astrochemical environments. To determine the potential effect that it has on the chemical mode…