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cond-mat.mtrl-sci2026

Huge hole injection in tungsten dichalcogenide heterostructures without electric gating: a DFT study

Dawid Ciszewski, Wojciech Grochala

Van der Waals heterostructures based on transition metal dichalcogenides, TMDs, provide a versatile platform for tailoring electronic properties through interlayer charge transfer,…

cond-mat.mtrl-sci2025

Chemical capacitor: its concept, functionalities and limits

Łukasz Wolański, Dawid Ciszewski, Piotr Szkudlarek +2

We use density functional theory calculations to study simple but diverse stoichiometries within the novel chemical capacitor (CC) setup. We look at main effects occurring in this…

cond-mat.mtrl-sci2025

Magnetic interactions as a pivotal determinant in stabilizing a novel AgIIAgIIIF5 polymorph with high spin AgIII

Daniel Jezierski, Wojciech Grochala

Based on theoretical calculations, we introduce a new AgIIAgIIIF5 monoclinic polymorph with a rare high spin AgIII. Our analysis of the experimental xray diffraction data available…

cond-mat.mtrl-sci2024

How orbitals and oxidation states determine apparent topographies in scanning tunneling microscopy: the case of fluorine on silver surfaces

Adrián Gómez Pueyo, Jazmín Aragón Sánchez, Ilya Degtev +11

We use density functional theory calculations to characterize the early stages of fluorination of silver's (100) and (110) surfaces. In the Ag(100) surface, the hollow site is the…

cond-mat.mtrl-sci2024

Controlling Orbital Ordering of Intergrowth Structures with Flat [Ag(II)F2] Layers to Mimic Oxocuprates(II)

Daniel Jezierski, Jose Lorenzana, Wojciech Grochala

Based on the Density Functional Theory calculations, we propose a new pathway toward compounds featuring flat [AgF2] layers which mimic [CuO2] layers in high-temperature oxocuprate…