most citedElectron Photodetachment from Aqueous Anions. III. Dynamics of Geminate Pairs Derived from Photoexcitation of Mono- vs. Poly- atomic Anions

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physics.chem-ph2005★ 65 cited

Electron Photodetachment from Aqueous Anions. III. Dynamics of Geminate Pairs Derived from Photoexcitation of Mono- vs. Poly- atomic Anions

Rui Lian, Dmitri A. Oulianov, Robert A. Crowell +3

Photostimulated electron detachment from aqueous inorganic anions is the simplest example of solvent-mediated electron transfer. Here we contrast the behavior of halide anions with…

physics.chem-ph2005★ 36 cited

Geminate recombination of hydroxyl radicals generated in 200 nm photodissociation of aqueous hydrogen peroxide

R. A. Crowell, R. Lian, M. C. Sauer +2

The picosecond dynamics of hydroxyl radicals generated in 200 nm photoinduced dissociation of aqueous hydrogen peroxide have been observed through their transient absorbance at 266…

physics.chem-ph2004★ 32 cited

Geminate recombination of electrons generated by above-the-gap (12.4 eV) photoionization of liquid water

Rui Lian, Dmitri A. Oulianov, Ilya A. Shkrob +1

The picosecond geminate recombination kinetics for hydrated electrons generated by 200 nm two photon absorption (12.4 eV total energy) has been measured in both light and heavy wat…

physics.chem-ph2004★ 25 cited

Light-induced temperature jump causes power-dependent ultrafast kinetics of electrons generated in multiphoton ionization of liquid water

Robert A. Crowell, Rui Lian, Ilya A. Shkrob +3

Picosecond geminate recombination kinetics for electrons generated by multiphoton ionization of liquid water become power dependent when the radiance of the excitation light is gre…

physics.chem-ph2004

Solvation, relaxation, and geminate recombination of electrons generated by two 200 nm photon ionization of liquid H2O and D2O

Rui Lian, Robert A. Crowell, Ilya A. Shkrob

Temporal evolution of transient absorption spectra for pre-solvated electron (e-) generated by biphotonic (200 nm) ionization of liquid H2O and D2O has been studied on femto- and p…

physics.chem-ph2004★ 45 cited

Electron Photodetachment from Aqueous Anions. II. Ionic Strength Effect on Geminate Recombination Dynamics and Quantum Yield for Hydrated Electron

Myran C. Sauer, Ilya A. Shkrob, Rui Lian +3

In concentrated solutions of NaClO4 and Na2SO4, the quantum yield for free electron generated by detachment from photoexcited anions (such as I-, OH-, ClO^4-, and [SO3]^2-) linearl…